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Next, we presume upon the design process exactly what we need to do to create an instrument, be it acoustic or electronic, which makes complete sense if you know where you want to go We need the piano hammers to strike when the associated key is pressed, and we need them to hit strings that are tuned to the pitch that their placement on the keyboard presumes that they should For the synth we ll need oscillators that can be filtered to sound like the tones decided in advance that we want, the tones we ll have printed on the case next to the tone buttons: bells, strings, flutes, all the things we presume people want to hear What makes alien worlds alien is that you can t presume what s there They operate outside the world of human knowing You cannot presume what they re going to do.

Fig. 2-20 Molecular ordering in nematic and smectic liquid crystals compared to liquid. After Brown and Crooker [1983] (by permission of American Chemical Society, Washington, DC).

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interest rate was fixed on all loans These maxima were altered only once in two thousand years Like early Sumerian custom, the Code set a higher maximum interest rate on loans of grain than on loans of silver Twelve hundred years later, circa 600 BC, the interest rate maximum on grain loans was reduced to equal the rate on silver loans Higher than maximum rates were occasionally permitted Very often, however, loans were negotiated below the maximum rates of interest To prevent violations, the Code required that all loan contracts be drawn up in the presence of an official and witnessed Otherwise the lender would lose all rights to repayment A higher than legal rate collected by subterfuge also canceled the debt Provision was made for compromise settlements when the debtor could not pay in full To protect the creditor, pledges and sureties were permitted.

Rigid-rod liquid crystal polymer molecules result from having rigid groups either within the polymer chain or as side groups on the polymer chain. These two types of LC polymers, referred to as main-chain and side-chain LC polymers, respectively, are depicted in Fig. 2-21. The rigid groups are referred to as mesogens or mesogenic groups. The mesogens are shown as rigid-rod groups, but other shapes (e.g., disks) are also possible. The collection of mesogenic units results in a molecule that is a rigid rod with molecular shape anisotropy and liquid crystal behavior. Liquid crystal behavior in polymers has practical consequences. Liquid crystal melts or solutions have lower viscosities than melts or solutions of random-coil polymers and are easier to process. More importantly, the extension and orientation of polymer chains during processing yields highly crystalline products with high modulus and high strength. The moduli and strengths of chain-extended LC polymers is considerably higher than those of

the chain-folded crystalline polymers formed from non-LC polymers. LC polymers also have signi cantly increased crystalline melting temperatures as a result of the extended-chain morphology. Thus, the synthetic guidelines are the same for synthesis of heat-resistant and LC polymers build rigid polymer chains. Poly(1,4-oxybenzoyl) (LII) [IUPAC: poly(oxy-1,4-phenylenecarbonyl), obtained by selfreaction of p-hydroxybenzoic acid, and the various aramids (Sec. 2-8f) were among the rst LC polymers studied. The experience in commercializing poly(1,4-oxybenzoyl) and the

aramids illustrates that one can have too much of a good thing None of these polymers can be melt processed since they undergo decomposition before melting (Tm > 500 C) The aramids are spin processed into bers using lyotropic solutions in sulfuric acid It would be preferable to melt-process the polymers or, at least, to use a less aggressive or less dangerous solvent, but these options do not exist Poly(1,4-oxybenzoyl) (Ekonol) has found limited utility due to a lack of easy processability It does not have suf cient solubility even in an aggressive solvent to allow solution processing It can be processed by plasma spraying or powder sintering There is a need to decrease the crystalline melting temperature in such very-high-melting LC polymers to achieve a degree of processability.

Pledging of farmland was regulated in detail; the creditor could not take more at harvest time than the principal, if due, plus legal interest Any property, real or personal, could be pledged wife, concubine, children, slaves, land, houses, utensils, credits, the door But servitude for debt could not last more than three years Later this time limit was extended Many contracts show that interest (and sometimes principal) on a debt was earned by the labor of a pledged slave or child The debtor, unable to pay, might himself be reduced to slavery for three years More often an indemnity was provided Provision was made for court settlement if there were several unsatisfied creditors The wife s signature was often required in a loan contract Women s property rights were protected by the Code; the husband alone could not pledge or dispose of joint property.

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